Interfacial oxidation of hafnium modified NiAl alloys

نویسندگان

چکیده

The high-temperature oxidation of Hf-modified NiAl alloy at 950 °C results in the formation γ-Al2O3 and θ-Al2O3. Exclusive HfO2 particles is observed adherent γ-Al2O3/NiAl interface. By contrast, θ-Al2O3/NiAl interface multi-layered oxide growth consisting alternate thin thick layers θ-Al2O3 NiAl2O4 along with dispersed layers. This difference elucidated by first-principle calculations showing that lattice more favorable than to host Hf Ni atoms, thereby resulting mixed oxides

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ژورنال

عنوان ژورنال: Corrosion Science

سال: 2021

ISSN: ['1879-0496', '0010-938X']

DOI: https://doi.org/10.1016/j.corsci.2021.109604